Combustion Characteristics of Low Calorific Value Biogas and Reaction Path of NOx Based on Sensitivity Analysis

Zongliang Zuo; Chuanjia Qi; Jinshuang Ma; Huiping Sun; Siyi Luo; Dongdong Ren; Yifan Zhang; Jianxiang Guo; Zhanjun Cheng; Chang Li

doi:10.3389/fchem.2021.830329

Combustion Characteristics of Low Calorific Value Biogas and Reaction Path of NOx Based on Sensitivity Analysis

Front Chem. 2022 Feb 16:9:830329. doi: 10.3389/fchem.2021.830329. eCollection 2021.

Authors

Zongliang Zuo^{1

2}, Chuanjia Qi^{1

2}, Jinshuang Ma¹, Huiping Sun¹, Siyi Luo¹, Dongdong Ren¹, Yifan Zhang¹, Jianxiang Guo¹, Zhanjun Cheng³, Chang Li¹

Affiliations

¹ School of Environmental and Municipal Engineering, Qingdao University of Technology, Qingdao, China.
² School of Energy and Power Engineering, Shandong University, Jinan, China.
³ School of Environmental Science and Engineering, Tianjin University, Tianjin, China.

Abstract

The combustion mechanism of biogas mixture is unclear, which leads to the lack of basis for the control of operating parameters. Combustion characteristics and reaction path of typical low calorific value biogas with variation of preheating temperature and air equivalence ratio (Φ) are discussed in this paper. Preheating can not only improve the flame propagation speed and flame temperature, but also increase the proportion of NO in the product at the end of combustion flame. To some extent, improving combustion efficiency and NOx control are contradictory operating parameters. The amount of NO increases with the increase in flame distance. The maximum value of NO appears when Φ is 1.1. NO formation rate is improved by preheating the biogas. The paths of N₂ → N₂O →NO, N₂ → NNH →NO, and N₂ →NO are all enhanced. When the equivalence ratio changes from 1.0 to 0.8, NO formation rates decrease.

Keywords: NOX; biogas combustion; biomass; reaction path; sensitivity analysis.