Antimonate is the dominant form of antimony (Sb) in Sb mine water. The treatment of high-Sb mine water essentially reduces the discharge of antimonate oxyanions ([Sb(OH)6]-) in it. Biochar obtained from phosphogypsum-modified anaerobic digested distillers' grain (PADC) can effectively adsorb antimonate from water. In this work, using batch adsorption experiments, mathematical models, and characterization methods, the mechanism of Sb(V) adsorption by PADC was studied. Compared with pristine biochar, PADC biochar showed abundant lamellar and vesicular structures with significant calcium ion loading on the surface. The kinetics data of the adsorption of Sb(V) on the PADC biochar followed the Elovich equation (R2 = 0.992), indicating that heterogeneous adsorption had occurred. The results also showed that intraparticle diffusion played an important role in controlling Sb(V) adsorption by PADC biochar. The Redlich-Peterson model best fit the Sb(V) adsorption isotherm (R2 = 0.997), indicating that the adsorption was a combination of the Langmuir and Freundlich models. The maximum adsorption capacity of PADC biochar for Sb(V) is 8123 mg/kg, which is more than twice that of the pristine biochar (3487 mg/kg) and is sufficient for Sb(V) treatment in most mine water. Fourier transform infrared (FTIR) spectra, X-ray photoelectron spectroscopy (XPS), X-ray diffractometry (XRD), and Transmission electron microscopy with energy dispersive X-ray spectroscopy (TEM-EDS) analyses revealed that the dominant mechanism of Sb(V) removal by PADC biochar was the formation of Ca-O-Sb complexes or amorphous surface precipitation as well as electrostatic adsorption. This work demonstrated the potential of PADC biochar in the treatment of Sb-contaminated mine water.
Keywords: Adsorption mechanisms; Antimonate removal; Modified biochar; Oxyanions.
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