Biochemical Μethane potential of most promising agricultural residues in Northern and Southern Greece

Abstract

Greece produces significant amounts of residual biomass due to its intense agricultural and agro-industrial sector. The anaerobic digestion process has been frequently considered as the best environmental and economic solution for energy recovery from different biodegradable waste such as agricultural waste, livestock manure, agro-industrial waste, as well as for their co-digestion. The aim of this study was the assessment of biochemical methane potential (BMP) of biomass feedstocks representative of Northern and Southern Greece, which are available during the fall/winter and spring/summer seasons, through the implementation of BMP assays. The raw residues evaluated in the current work included: (a) crop residues (corn silage and unsuitable for human consumption watermelon), (b) agro-industrial residues (malt, tomato processing residues, orange peels and olive pomace) and (c) livestock (cattle) manure. Tests of both single substrates and various mixtures were conducted for the evaluation of their methane yields. The results of the mono-substrates are in accordance with other studies in the literature, with watermelon presenting the highest methane potential (421.0 ± 3.4 ml CH₄/g VS_added). After the evaluation of the mixtures and mono-substrates results, the most promising mixtures seemed to be the following: a) for Northern Greece, 10% corn silage-80% cattle manure-10% malt, b) for Southern Greece spring/summer season, 10% corn silage-14% cattle manure-66% watermelon-10% tomato processing residues, and c) for Southern Greece fall/winter season, 10% corn silage-57% cattle manure-23% orange peels-10% olive pomace.

Keywords: Biochemical methane potential (BMP) assays; Cattle manure; Corn silage; Olive pomace; Orange peels; Tomato processing residues.