Metal-organic frameworks (MOFs) provide broad prospects for the development of new photothermal conversion materials, while their design and synthesis remain challenging. A new Zn-MOF (1) containing both tetrathiafulvalene (TTF) as an electron donor and naphthalene diimide (NDI) as an electron acceptor was constructed by using a space limiting effect. The material exhibited wide absorption peaks in the near-infrared region, indicating that there was strong charge transfer interaction between the TTF and NDI units and providing the possibility of photothermal conversion. 1 shows efficient near-infrared photothermal conversion performance. Under 808 nm laser (0.4 W cm-2) illumination, the temperature of 1 increased rapidly from room temperature to 250 °C, with good thermal stability and cycle durability. This work provides an efficient strategy for promising materials in photothermal therapy.