Geographical identification of strawberries based on stable isotope ratio and multi-elemental analysis coupled with multivariate statistical analysis: A Slovenian case study

Food Chem. 2022 Jul 1:381:132204. doi: 10.1016/j.foodchem.2022.132204. Epub 2022 Jan 21.

Abstract

The geographical classification and authentication of strawberries were attempted using discriminant and class-modelling methods applied to stable isotopes of light elements and elemental composition. The work involved creating a database of 92 authentic Slovenian strawberry samples and 32 imported samples. All samples were harvested between 2018 and 2020. A good geographical classification of Slovenian and non-Slovenian strawberries was obtained despite different production years using discriminant approaches. However, for verifying compliance with a given specification (geographical indications), a class-modelling approach was used to build an unbiased verification model. Class models generated by data-driven soft independent modelling of class analogy (DD-SIMCA) had high sensitivity (96% to 97%) and good specificity (81% to 91%) on a yearly basis, while a more generalised model combining total yearly data gave a lower specificity (63%). Of the 33 commercially available samples (test samples) with declared Slovenian origin, 39% were from outside of Slovenia.

Keywords: Authenticity; DD-SIMCA; Element composition; Geographical origin; Stable isotope; Strawberries.

MeSH terms

  • Discriminant Analysis
  • Fragaria*
  • Geography
  • Isotopes / analysis
  • Slovenia

Substances

  • Isotopes