Vacancy and interface engineering are regarded as effective strategies to modulate the electronic structure and enhance the activity of metal chalcogenides. However, the practical application of metal chalcogenides in lithium-sulfur (Li-S) batteries is limited by their low conductivity, rapid decline in catalytic activity, and large volume variation during the discharging/charging process. Herein, bimetal sulfide (CoZn-S) nanosheet arrays with sulfur vacancies and dense heterointerfaces are proposed to accelerate sulfur conversion and improve the performance of Li-S batteries. Systematic investigations reveal that sulfur-vacancy and build-in interfacial field in CoZn-S facilitate the electron transfer and regulate the electronic structure. The well-designed 3D nanosheet array structures shorten the ion-transport pathway and inhibit the volume fluctuation of CoZn-S during the electrocatalysis process. Density functional theory studies confirm that the built-in interfacial field and sulfur vacancy can promote the thermodynamic formation and decomposition of Li2 S, thus improving their intrinsic activity.
Keywords: bimetal chalcogenides; electrocatalysis; heterointerfaces; sulfur conversion; vacancies.
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