Bifunctional rare metal-free electrocatalysts synthesized entirely from biomass resources

Sci Technol Adv Mater. 2022 Jan 18;23(1):31-40. doi: 10.1080/14686996.2021.2020597. eCollection 2022.

Abstract

The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are important processes for various energy devices, including polymer electrolyte fuel cells, rechargeable metal-air batteries, and water electrolyzers. We herein report the preparation of a rare metal-free and highly efficient ORR/OER electrocatalyst by calcination of a mixture of blood meal and ascidian-derived cellulose nanofibers. The obtained carbon alloys showed high ORR/OER performances and proved to be promising electrocatalysts. The carbon alloys synthesized entirely from biomass resources not only lead to a new electrocatalyst fabrication process but also contribute to CO2 reduction and the realization of a good life-cycle assessment value in fabrication of a sustainable energy device.

Keywords: 50 Energy Materials, 103 Composites < 100 Materials; Biomass resources; cellulose nanofibers; electrocatalysts; oxygen evolution; oxygen reduction.

Grants and funding

This work was supported by the JSPS (Japan Society for the Promotion of Science) [18H05482, 19KK0357, 20H04625]; Japanese Ministry of Education Culture, Sports, Science and Technology [‘Five-Star-Alliance’]; New Energy and Industrial Technology Development Organization [2020-0115004].