A review of volatile organic compounds (VOCs) degradation by vacuum ultraviolet (VUV) catalytic oxidation

Abstract

Volatile organic compounds (VOCs), one of the most important gaseous air pollutants, are getting more and more attention, and a lot of technologies have been studied and applied to eliminate VOCs emissions. Advanced oxidation processes (AOPs) are considered as one of the most promising techniques used for the degradation of VOCs. Vacuum ultraviolet (VUV) catalytic oxidation system is a typical composite AOPs system involving several processes such as VUV photodegradation, photocatalytic oxidation (PCO), ozone catalytic oxidation (OZCO) and their combinations. VUV based catalytic oxidation processes have been intensively studied for degrading VOCs. This review summarizes the recent studies on the use of VUV catalytic oxidation for degrading VOCs. All the processes involved in VUV catalytic oxidation and their combinations have been reviewed. Studies of VOCs degradation by VUV catalytic oxidation can be generally divided into two aspects: developments of catalysts and mechanistic studies. Principles of different processes, strategies of catalyst development and reaction mechanism are summarized in this review. Two directions of prospective future work were also proposed.

Keywords: Catalytic ozonation; Ozone; Photocatalysis; Photolysis; VOCs; VUV.