In this work, we investigate the change of contact angle (CA) of a water droplet during evaporation on a Teflon AF1600 surface in the temperature range between 20 and 80 °C under standard laboratory conditions. An almost constant initial CA and a significant increase of the stabilized CA have been observed. The results reveal a temperature-dependent CA change, mainly due to water adsorption on the solid surface. Soaking experiments indicate that besides adsorption, a temperature-independent friction-like force contributes to the pinning of triple-line and therefore to the CA change. We propose an adsorption coverage parameter and a friction-like force to describe the CA change. Furthermore, we describe a reproducible process to produce smooth and homogeneous Teflon AF1600 thin films, minimizing the influence of roughness and local heterogeneity on the CA.