In this study, FeMg-LDH loaded with bentonite (FeMg-LDH@bentonite) was prepared using the facile co-precipitating method in situ to remove heavy metals from water and then characterized using XRD, SEM, TEM, FTIR, BET, TGA, and XPS. Pb (II) and Cd (II) were selected as the representative heavy metals to evaluate the adsorption capability of the FeMg-LDH@bentonite. The batch adsorption method was adopted to test the effects of the contact time, pH, initial concentration, different cations, and temperatures. The kinetic study indicated that the adsorption of heavy metals onto FeMg-LDH@bentonite was well fitted by the pseudo-second-order method. Isotherms were effectively simulated based on the Langmuir model. The maximal adsorption capability of Cd (II) and Pb (II) can reach 510.2 mg/g and 1397.62 mg/g, exceeding those of conventional adsorbents. The adsorption mechanisms of FeMg-LDH@bentonite demonstrating that there may exist surface complexation, ion exchange, and chemical deposition between FeMg-LDH@bentonite and heavy metals. Moreover, FeMg-LDH@bentonite was found to have a promising application for practically treating wastewater with heavy metals and can be used for various environmental water pollution treatments. The material may be used for heavy metal contaminated soil in the future.
Keywords: Adsorption mechanism; Heavy metal removal; Layered double hydroxide; Wastewater treatment.
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