Nanometer-Thick Superhydrophobic Coating Renders Cloth Mask Potentially Effective against Aerosol-Driven Infections

ACS Appl Bio Mater. 2021 Nov 15;4(11):7921-7931. doi: 10.1021/acsabm.1c00851. Epub 2021 Oct 13.

Abstract

The advent of COVID-19 pandemic has made it necessary to wear masks across populations. While the N95 mask offers great performance against airborne infections, its multilayered sealed design makes it difficult to breathe for a longer duration of use. The option of using highly breathable cloth or silk masks especially for a large populace is fraught with the danger of infection. As a normal cloth or silk mask absorbs airborne liquid, it can be a source of plausible infection. We demonstrate the chemical modification of one such mask, Eri silk, to make it hydrophobic (contact angle of water is 143.7°), which reduces the liquid absorption capacity without reducing the breathability of the mask significantly. The breathability reduces only 22% for hydrophobic Eri silk compared to the pristine Eri silk, whereas N95 shows a 59% reduction of breathability. The modified hydrophobic silk can repel the incoming aqueous liquid droplets without wetting the surface. The results indicate that a multilayered modified silk mask to make it hydrophobic can be an affordable and breathable alternative to the N95 mask.

Keywords: SARS-CoV-2; aerosol-driven infections; masks; octadecyltrichlorosilane; superhydrophobic.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Breath Tests
  • COVID-19 / prevention & control*
  • COVID-19 / virology
  • Humans
  • Hydrophobic and Hydrophilic Interactions
  • Masks*
  • Nanostructures / chemistry*
  • Porosity
  • Respiratory Protective Devices / virology
  • SARS-CoV-2 / isolation & purification
  • Silanes / chemistry
  • Silk / chemistry

Substances

  • Silanes
  • Silk
  • octadecyltrichlorosilane