Efficiency, by-product valorization, and pollution control of co-pyrolysis of textile dyeing sludge and waste solid adsorbents: Their atmosphere, temperature, and blend ratio dependencies

Abstract

This study aimed to quantify the co-pyrolytic synergistic effects of textile dyeing sludge (TDS) and waste biochar (WBC) for an optimal utilization of secondary resources and to mitigate environmental pollution and waste volume. TDS and WBC had a strong synergistic effect between 800 and 900 °C in the CO₂-assisted atmosphere. With the increased TDS fraction, NH₃ emission fell significantly regardless of the atmosphere type. The CO₂ atmosphere changed S in TDS char and released SO₂ in the range of 800-1000 °C. With the temperature rise, an unstable N structure turned into a more stable heterocyclic N structure in the CO₂ and N₂ atmospheres. Regardless of the atmosphere type and temperature, the C-containing functional groups in co-pyrolytic biochar existed mainly as C-C/C-H. In the CO₂ atmosphere, inorganic S, aliphatic S, and thiophene S in the co-pyrolytic biochar disappeared and became more stable sulfones. The co-pyrolysis inhibited the formation of S-containing compounds. The retention ability of the co-pyrolytic biochar peaked for most of the heavy metals in the N₂ atmosphere but was better for Pb and Zn in the CO₂ than N₂ atmosphere. Simultaneous optimization showed the co-pyrolysis of 10% TDS and 90% WBC at above 950 °C in the N₂-CO₂ or CO₂ atmosphere as the optimal operational settings combined.

Keywords: Bio-oils; Co-pyrolysis; Joint optimization; Textile dyeing sludge; Waste biochar.