New insights into iron/nickel-carbon ternary micro-electrolysis toward 4-nitrochlorobenzene removal: Enhancing reduction and unveiling removal mechanisms

Abstract

The ternary micro-electrolysis material iron/nickel-carbon (Fe/Ni-AC) with enhanced reducibility was constructed by introducing the trace transition metal Ni based on the iron/carbon (Fe/AC) system and used for the removal of 4-nitrochlorobenzene (4-NCB) in solution. The composition and structures of the Fe/Ni-AC were analyzed by various characterizations to estimate its feasibility as reductants for pollutants. The removal efficiency of 4-NCB by Fe/Ni-AC was considerably greater than that of Fe/AC and iron/nickel (Fe/Ni) binary systems. This was mainly due to the enhanced reducibility of 4-NCB by the synergism between anode and double-cathode in the ternary micro-electrolysis system (MES). In the Fe/Ni-AC ternary MES, zero-iron (Fe⁰) served as anode involved in the formation of galvanic couples with activated carbon (AC) and zero-nickel (Ni⁰), respectively, where AC and Ni⁰ functioned as double-cathode, thereby promoting the electron transfer and the corrosion of Fe⁰. The cathodic and catalytic effects of Ni⁰ that existed simultaneously could not only facilitate the corrosion of Fe⁰ but also catalyze H₂ to form active hydrogen (H*), which was responsible for 4-NCB transformation. Besides, AC acted as a supporter which could offer the reaction interface for in-situ reduction, and at the same time provide interconnection space for electrons and H₂ to transfer from Fe⁰ to the surface of Ni⁰. The results suggest that a double-cathode of Ni⁰ and AC could drive much more electrons, Fe²⁺ and H*, thus serving as effective reductants for 4-NCB reduction.

Keywords: 4-Nitrochlorobenzene; Active hydrogen; Iron corrosion; Reducibility; Ternary micro-electrolysis.