The controllability study is an integral part of chemical process design. In this work, the controllability of two special distillation techniques, extractive distillation and pressure swing distillation, designed for the separation of azeotropic mixtures is investigated with dynamic tools. The control design interface of Aspen Plus and Matlab are applied for the modeling and evaluation of the two systems. Dynamic controllability indices are determined and aggregated in a desirability function. The results are compared to obtain efficient help for process design activity. The pressure swing distillation shows significantly better controllability features than the extractive distillation. The reason can be the fact that in the case of the extractive distillation, a third compound, the extractive agent, is added to the system to carry out the separation, therefore making the system more complex. As far as the selection of manipulated variables is concerned, in the case of the extractive distillation, the reflux flows should be preferred to the reflux ratios but in the case of the pressure swing distillation, the reboiler heat loads are preferred to the reflux ratios since those are closer to the controlled compositions. Both separation systems show worse controllability features if the product purity requirement is approaching to the pure products, that is, close to 100%. Although the energy consumption of the pressure swing distillation is higher than that of the extractive distillation, it has the inherent feature that it can be automatically heat integrated due to a column operated at high pressure and, as a consequence, higher temperatures.
© 2021 The Authors. Published by American Chemical Society.