Ecological evaluation of heavy metal pollution in the soil of Pb-Zn mines

Abstract

Soil heavy metal pollution evaluations are a necessary measure for mine ecological control projects. In this study, the heavy metals Pb, Zn and Cd were studied in mining areas, tailings areas, sewage plant areas, residential areas, reclamation areas, and farmland areas. Soil pollution assessments of lead-zinc ore mine soils in the countryside of China are performed based on the index of geoaccumulation (I_geo) and the improved analytic hierarchy process (AHP). Finally, the pollution sources were analyzed by positive matrix factorization (PMF). The I_geo for the heavy metals Pb, Zn and Cd in the mining area reached 5.20, 3.34, and 5.66, respectively. In addition, 80 and 65% of the mining area and tailings area reached extremely strong pollution, respectively. The numerical simulation predicts that the pollution hazard in the southeast of the mine is high and that the pollution is concentrated. The severity of soil pollution in mines derived by the index of improved analytic hierarchy process (P_AHP) was as follows: mining area (70.80) > sewage plant area (35.57) > tailings area (30.64) > farmland area (28.40) > residential area (21.11) > reclamation area (10.06). Among the three categories of pollution sources, one includes reclamation area, farmland area and tailings area; one includes sewage plant area and residential area; and one includes mining area. The source contribution of Pb by the phenomenon of indiscriminate discharge of wastewater after ore smelting was as high as 90.4%; The contribution of the blind mining and tailings piling phenomenon of mines to the source of heavy metals Zn and Cd was 81.4 and 90.2%, respectively. This study proposes a reliable scientific method and technical method for evaluating mine soil pollution and provides a guiding basis for mine development and protection.

Keywords: Heavy metal pollution; Improved analytic hierarchy process; Index of geoaccumulation; Mine soils; Positive matrix factorization.