The widespread use of methyl parathion (MP) and carbendazim (CBZ) as pesticide molecules for controlling pests and protect crops has added pollution issues; excess usage of these can lead to atmospheric pollution through contaminating water and soil sources. In the present study, detection of these compounds at the trace level was achieved by employing graphene oxide (GO) and graphitic carbon nitride (g-C3N4) nanohybrid electrode assembly (GO/g-C3N4/GCE). The X-ray diffraction (XRD), Transmission Electron Microscopy (TEM), and Atomic Force Microscopy (AFM) techniques were also used to characterize the materials developed to reveal their purity, crystal structure, and morphology. The complete voltammetric behavior of these analytes was investigated using cyclic voltammetic (CV) and square wave voltammetry (SWV) techniques. The influence of pH was studied and it was noticed that electrochemical response was the highest at pH 7.0 for MP and at pH 4.2 for CBZ. Density Functional Theory (DFT) calculations could help us to understand the adsorption behavior of MP and CBZ onto the GO and g-C3N4 before their degradation due to the electrochemical reactions. SWV technique was helpful in the trace level detection of MP and CBZ. Linearity plots were obtained in the range of concentration from 8.0 × 10-8 M to 1.0 × 10-4 M with a limit of detection 0.824 nM for MP and 1.0 × 10-8 M to 2.5 × 10-4 M for CBZ with the detection limit of 2.82 nM. Significance of the developed method in the field of agricultural and environmental domains was successfully investigated by monitoring MP and CBZ in water and soil samples, and the obtained results suggested the selectivity, stability, and reproducibility of the newly developed GO/g-C3N4/GCE electrode assembly.
Keywords: Carbendazim; DFT; Electrochemical sensor; Environmental sample analysis; Methyl parathion; Temperature effect.
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