This theme issue, in two parts, continues research studies of transport phenomena in complex media published in the first part (Alexandrov & Zubarev 2021 Phil. Trans. R. Soc. A 379, 20200301. (doi:10.1098/rsta.2020.0301)). The issue is concerned with theoretical, numerical and experimental investigations of nonlinear transport phenomena in heterogeneous and metastable materials of different nature, including biological systems. The papers are devoted to the new effects arising in such systems (e.g. pattern and microstructure formation in materials, impacts of external processes on their properties and evolution and so on). State-of-the-art methods of numerical simulations, stochastic analysis, nonlinear physics and experimental studies are presented in the collection of issue papers. This article is part of the theme issue 'Transport phenomena in complex systems (part 2)'.
Keywords: biophysical systems; complex systems; heterogeneous materials; metastable and non-equilibrium systems; phase transformations; transport phenomena.