Waste preserved wood derived biochar catalyst for promoted peroxymonosulfate activation towards bisphenol A degradation with low metal ion release: The insight into the mechanisms

Abstract

The rational disposal of waste preserved wood is of great significance since its embedded metals (Cu, As, and Cr) pose potential threat to environment and human health. In this study, a biochar catalyst derived from waste preserved wood (PWB) was prepared for the degradation of bisphenol A (BPA) via peroxymonosulfate (PMS) activation. The PWB exhibited prominent catalytic degradation capability towards BPA compared with common wood derived biochar (CWB). Further tests and analysis elucidated that both radical species (OH) and non-radical species (¹O₂) were generated by the PWB/PMS system, whereas only ¹O₂ was detected in CWB/PMS system. Specifically, the metal compounds, especially metallic Cu in the PWB activated PMS via radical pathway, and the CO groups in the biochar generated the non-radical pathway, the coexistence of which resulted in higher BPA degradation rate in PWB/PMS system. It was also demonstrated that the heavy metal ion leaching (As and Cr) in PWB/PMS system was negligible. Furthermore, the biochar could effectively inhibit the leakage of oxidized Cu ions. This study provides a novel approach to prepare high-efficient carbocatalysts for organic pollutant degradation in water, which also enables the waste preserved wood with an environmental nondestructive mode of dispatch.

Keywords: Biochar catalyst; Low metal leaching; Peroxymonosulfate; Preserved wood; Radical/non-radical synergy.