Response to the Temperature and Solvent Stimulation of MOF Material in a Single-Crystal to Single-Crystal Manner

Jian-Lei Qian; Tao Zhou; Xin Lu; Heng Xu; Jia-Yin Sun; Chuan-Lei Zhang; He-Gen Zheng

doi:10.1021/acs.inorgchem.1c03615

Response to the Temperature and Solvent Stimulation of MOF Material in a Single-Crystal to Single-Crystal Manner

Inorg Chem. 2022 Jan 10;61(1):47-51. doi: 10.1021/acs.inorgchem.1c03615. Epub 2021 Dec 22.

Authors

Jian-Lei Qian¹, Tao Zhou¹, Xin Lu¹, Heng Xu¹, Jia-Yin Sun¹, Chuan-Lei Zhang^{1

2}, He-Gen Zheng²

Affiliations

¹ AnHui Province Key Laboratory of Optoelectronic and Magnetism Functional Materials, Key Laboratory of Functional Coordination Compounds of Anhui Higher Education Institutes, Anqing Normal University, Anqing 246133, P. R. China.
² State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, P. R. China.

PMID: 34935390
DOI: 10.1021/acs.inorgchem.1c03615

Abstract

Under solvothermal conditions, a three-dimensional mononuclear crystal AQNU-1, {[Co(H₂L)(DPD)(H₂O)₂]·2DMA}_n (H₂L = 5-(bis(4-carboxybenzyl)amino)isophthalic acid, DPD = 4,4'-(2,5-diethoxy-1,4-phenylene)dipyridine) has been synthesized. The transformations of AQNU-1 to binuclear {[Co₂(L)(DPD)_1.5(H₂O)₃]·DMA·H₂O}_n (AQNU-2) and pentanuclear {[Co₅(L)₂(DPD)₂(OH)₂]·2H₂O}_n (AQNU-3) were realized by double stimulation of temperature and solvent, which were accomplished by single-crystal to single-crystal (SC-SC) reaction.