Remediation of cadmium contaminated soil by modified gangue material: Characterization, performance and mechanisms

Abstract

Nowadays, remediation of soil contaminated with potentially toxic metal is a great international concern. In this study, a novel modified gangue material (MGE) is synthesized from coal gangue (GE) through a low-temperature assisted with alkali roasting method, and is applied to the immobilization of cadmium (Cd²⁺) in contaminated soil. The various instruments (SEM-EDS, FTIR, XRD, TGA, and XPS) are employed to investigate the changes of microstructure and function of GE before and after the modification. The results showed that a large number of active groups (Si-O, Al-O, Fe-O, -OH, -CO, and -COOH) are observed on the surface of MGE, which is conducive to the removal of Cd²⁺. Besides, the adsorption kinetics, and isotherm models are introduced to analyze the potential adsorption mechanism, which suggesting that the adsorption behavior can be well fitted by pseudo-second-order and Langmuir models. The potential mechanisms of MGE include the ion exchange, complexation, electronic attraction, and precipitation. According to the pot experiment, the application of MGE can significantly improve the growth of pakchoi, and increase the pH of soils. Meanwhile, the content of available Cd²⁺ is reduced in the treatment with MGE, by a factor of 14.2%-29.8%. Correspondingly, the content of Cd²⁺ in different parts of pakchoi is also decreased. The study shows that the MGE can be strongly recommended as an efficient and safe amendment to stabilize Cd²⁺ in contaminated soil.

Keywords: Cadmium immobilization; Cadmium pollution; Coal gangue; Soil remediation.