Adsorption behavior of fluoroquinolone(ciprofloxacin) using zinc oxide impregnated activated carbon prepared from jack fruit peel: Kinetics and isotherm studies

Abstract

Ciprofloxacin is a pharmaceutical component used for treating various tract infections. This is considered as an emerging contaminant due to the release of unreacted components getting disposed into the water bodies. This component is effectively treated using renewable biomass, which is converted into a useful renewable low-cost adsorbent material. Discarded Jack Fruit Peel (JFP) is used as an activated carbon incorporated with zinc oxide nanocomposite. The prepared activated carbon in this experiment was characterized by determining their functional groups, morphological characters, and nature of the adsorbent material by analyzing the Fourier Transform InfraRed (FTIR), Field Emission Scanning Electron Microscopy (FESEM), and X-ray Diffraction (XRD) characterization. Further, the prepared composite's correlation coefficients and equilibrium sorption of the adsorption process were calculated using Ultra Violet (UV)-Visible Spectroscopy and analyzed with isotherm models (Langmuir model, Freundlich model, and Temkin model) and kinetic models (Pseudo-first-order kinetics, Pseudo-second-order kinetics, Intraparticle diffusion model, and Elovich model). Among the different models, the Zinc oxide impregnated activated carbon show Freundlich Isotherm and Pseudo Second order equation having a maximum correlation with experimental studies indicating double-layer adsorption, which suggests that the process is chemisorption. The operational parameters, including the effect of pH, dosage of activated carbon, and contact time of adsorption was calculated to identify the optimal condition for maximum adsorption.

Keywords: Adsorption; Biomass; Pharmaceutical component; Wastewater treatment.