Fly ash and H2O2 assisted hydrothermal carbonization for improving the nitrogen and sulfur removal from sewage sludge

Abstract

In this study, fly ash and hydrogen peroxide (H₂O₂) assisted hydrothermal carbonization (HTC) was used to improve the removal efficiency of nitrogen (N) and sulfur (S) from sewage sludge (SS). The removal rate and distribution of N and S in hydrochar were evaluated, and properties of the aqueous phase were analyzed to illustrate the N and S transformation mechanism during fly ash and H₂O₂ assisted HTC treatment of SS. The results suggested that during HTC process assisted by fly ash (10% of raw SS), dehydration, decarboxylation and hydrolysis of SS were strengthened due to the catalysis effect. The N and S removal were promoted marginally. For hydrochar achieved from HTC process with H₂O₂ addition, the N and S removal were improved slightly due to the biopolymer oxidization by ‧OH released from H₂O₂ decomposition. While for HTC treatment with fly ash and H₂O₂ supplementation, a positive synergistic effect on N and S removal was observed. The N and S removal obtained from fly ash (10% of raw SS) and H₂O₂ (48 g/L) assisted HTC increased to 81.71% and 62.83%, respectively, from those of 69.53% and 49.92% in control group. N and S removal mechanism analysis suggested that hydroxyl radicals (‧OH) produced by H₂O₂ decomposition will destroy SS structure, and the biopolymers such as polysaccharides and proteins will be decomposed to release N and S into the liquid residue. In addition, the fly ash acts as the catalyst will decrease the energy need for denification and desulfartion. Consequently, N and S removal efficiency was enhanced by fly ash and H₂O₂ assisted HTC treatment.

Keywords: Fly ash; Hydrochar; Hydrogen peroxide; Hydrothermal carbonization; Sewage sludge.