Considering that the processes of PEEK discoloration caused by either intrinsic or extrinsic factors require elucidation, the aim of this study was to investigate the long-term effect of the combined action of ageing and immersing solutions on the optical properties and color stability of PEEK material, related to surface processing (polishing or glazing). (2) Methods: This study aims to determine the influence of different ageing and staining protocols on optical properties, color changes, and surface roughness of a reinforced PEEK material (bioHPP, Bredent, Senden, Germany). For ageing, specimens were submitted to 5000 cycles in a 55 °C bath and a 5 °C bath filled with distilled water. For staining, thermal cycling was performed in a hot coffee bath (55 °C) and a bath filled with distilled water (37 °C) and in a cold juice bath (5 °C) and a bath filled with distilled water (37 °C). Translucency (TP) and opalescence (OP) parameters were determined, the total color change value (ΔΕ*) was calculated, specimens' surface roughness was analyzed, and statistical analyses were performed. (3) Results: The mean TP values of the studied samples were in the interval of 1.25-3.60, which is lower than those reported for natural teeth or other aesthetic restoration materials. The OP values of PEEK were registered in the range of 0.27-0.75, being also lower than those of natural teeth or other aesthetic restoration materials. OP has a very strong positive relationship with TP. The mean registered Ra values for all subgroups were below 0.13 µm. Artificial ageing and staining in hot coffee proved to increase the roughness values. (4) Conclusions: The glazing of PEEK has a favorable effect on surface roughness and opalescence, irrespective of the artificial ageing or staining protocols. Artificial ageing damages the color stability and roughness of PEEK, regardless of surface processing, and decreases the translucency and opalescence of glazed surfaces. Immersion in hot coffee leads to perceivable discolorations.
Keywords: artificial ageing; color stability; dental polyetheretherketone; optical properties; staining.