Products distribution and pollutants releasing characteristics during pyrolysis of waste tires under different thermal process

Abstract

Pyrolysis has been widely utilized to achieve resource recovery of waste tires by attaining oil and carbon black. However, due to the stacking effect of fixed bed, the heat and mass transfer is insufficient during the pyrolysis process of waste tires. Additionally, the harmful N/S/Cl pollutants and heavy metals are inevitable that has been ignored. This paper systematically studied the effect of promoting heat and mass transfer on the oil quality and pollutant releasing characteristics during the pyrolysis of waste tires. A fixed bed pyrolizer with multifunction was innovatively designed to conduct fast pyrolysis by equipping an intermittent feeder and slow pyrolysis by equipping an agitator. Fast pyrolysis with feeding step by step and slow pyrolysis with stirring could promote the heat and mass transfer, which was firstly researched in lab-scale reactor. The experimental results demonstrated that slow pyrolysis with stirring was recommended with the target of acquiring pyrolytic oil. Promoting heat and mass transfer could improve the quality of oil and increase the retaining proportion of S in char during both fast and slow pyrolysis. The combustion of pyrolysis oil and gas generated more dioxins (0.6 ng/g_wt) than the total dioxins in pyrolytic gas and oil (0.06 ng/g_wt).

Keywords: Dioxins; Hazardous elements; Heavy metals; Pyrolysis; TG-IR-GC/MS; Waste tires.