Fractal Characteristics and Significance of Different Pore Types of the Wufeng-Longmaxi Formation, Southern Sichuan Basin, China, Based on N2 Adsorption and Image Analysis

Yang Chen; Hongming Tang; Majia Zheng; Changsheng Li; Shengxian Zhao; Ning Zhao; Yijiang Leng

doi:10.1021/acsomega.1c02539

Fractal Characteristics and Significance of Different Pore Types of the Wufeng-Longmaxi Formation, Southern Sichuan Basin, China, Based on N₂ Adsorption and Image Analysis

ACS Omega. 2021 Nov 10;6(46):30889-30900. doi: 10.1021/acsomega.1c02539. eCollection 2021 Nov 23.

Authors

Yang Chen¹, Hongming Tang¹, Majia Zheng^{1

2}, Changsheng Li¹, Shengxian Zhao², Ning Zhao¹, Yijiang Leng¹

Affiliations

¹ School of Geoscience and Technology, Southwest Petroleum University, Chengdu 610500, China.
² PetroChina Southwest Oil & Gas Field Company, Chengdu 610051, China.

Abstract

Shale gas is an important unconventional natural gas resource, and its reservoirs have pores with strong heterogeneity, which have an important effect on the adsorption and migration of shale gas, but the specific mechanism is still unclear. To further clarify the pore structure characteristics of shale gas reservoirs and the mechanism of their influence on CH₄ adsorption capacity, marine shale samples from the Wufeng-Longmaxi formation of wells N1, N3, and N10 in Changning block, southern Sichuan Basin, China, were selected for total organic carbon (TOC), X-ray diffraction (XRD), N₂ gas adsorption (N₂-GA), CH₄ gas adsorption (CH₄-GA), and field emission scanning electron microscopy (FE-SEM). The Frenkel-Halsey-Hill (FHH) model and Slit Island Analysis (SIA) were used to calculate the fractal dimension of the pore system and different types of pores, and their relationship and influence on CH₄ adsorption capacity were also discussed. The results show that the fractal dimension could reflect the complexity and heterogeneity of pores. According to the FHH model, fractal dimensions of the surface and structure of the pore system (D ₁ and D ₂, D ₁ < D ₂) were obtained, and the pore structure was more complex than the pore surface. According to SIA, the surface fractal dimensions of four types of reservoir space (D _DP, D _OP, D _IP, and D _MF) decrease progressively, and their main body is 2.60-2.80, 2.40-2.65, 2.20-2.40, and 2.05-2.30. Organic pores and intergranular pores are the most abundant, and so D ₁ is mainly related to D _OP and D _IP. In high-TOC samples, D ₁ is close to D _OP, while in low-TOC samples, D ₁ is close to D _IP. The complexity of the pore surface, D ₁, and specific surface area have a positive correlation, and with the increase of pore surface complexity, methane adsorption capacity could be significantly improved. Therefore, D ₁ may be used as a characterization parameter of CH₄ adsorption capacity, which could provide some evidence to further clarify the adsorption mechanism of shale gas.