Derivatives of metal-organic frameworks for heterogeneous Fenton-like processes: From preparation to performance and mechanisms in wastewater purification - A mini review

Abstract

Organic pollution is an ever-growing issue in aquatic environment, Fenton-like processes have gained widespread acceptance due to their high oxidative potential and environmental compatibility. Derivatives of metal-organic frameworks (MOFs) are emerging heterogeneous Fenton-like catalysts, which have advantages of large surface area, diversity of structures, and abundant active sites. This work focuses on the recent advances in MOFs derivatives including metal compounds and metal incorporated carbons for Fenton-like processes. First, preparation strategies, structures and compositions are introduced. And then, the removal of organic pollutant in Fenton, electro-Fenton, and photo-Fenton process catalyzed by MOFs derivative is summarized, respectively. The contents particularly devote efforts to build connections among preparation, structures, compositions, and performance. Furthermore, the mechanisms of improving performance are discussed in detail. Finally, the perspectives of MOFs derivatives toward Fenton-like applications are proposed.

Keywords: Derivatives; Fenton-like; Heterogeneous catalysis; Metal-organic frameworks; Water purification.