Effective desalination of brackish groundwater using zeolitized diatomite/kaolinite geopolymer as low-cost inorganic membrane; Siwa Oasis in Egypt as a realistic case study

Abstract

The salinization of the groundwater wells in Siwa oasis, Egypt represents a critical environmental and economic issue. Developing low-cost, effective, and self-supported inorganic membranes were suggested as suitable desalination techniques. Zeolite/geopolymer (Z/GP) membrane was synthesized as a potential low-cost membrane for effective desalination of brackish groundwater in Siwa Oasis, Egypt. The membrane was synthesized by simple geopolymerization for natural kaolinite and diatomite at room temperature. This was followed by hydrothermal growth of zeolite at 100 °C for 24 h to produce zeolitized geopolymer as potential inorganic membrane. After that, the prepared membrane was incorporated in the pervaporation desalination system considering the effect of the membrane thickness and the temperature. The results demonstrated water flux values of 8.34 kg.m^-2.h^-1, 7.63 kg.m^-2.h^-1, and 7.05 kg.m^-2.h^-1 for the tested membrane at thicknesses of 1 mm, 2 mm, and 3 mm, respectively. This associated with significant salt rejection prearranges 95.8% (1 mm), 97.6% (2 mm), and 99.4% (3 mm). Moreover, the high-temperature value (90 °C) is of strong positive impact on the water flux (7.82 kg.m^-2.h^-1) and a slight impact on the salt rejection (99.6%). The membrane is of significant stability considering the obtained water flux (7.51 kg.m^-2.h^-1) and salt rejection (99.57%) after 130 h. The reusability properties of the Z/GP membrane demonstrated its suitability to be used in the desalination process for five runs. Therefore, the synthetic Z/GP membrane is a highly recommended product for simple, effective, low cost, and available desalination technique brackish groundwater in Siwa Oasis.

Keywords: Desalination; Geopolymer; Groundwater; Pervaporation; Siwa Oasis; Zeolite membrane.