Fabrication and characterization of chitosan-CeO2-CdO nanocomposite based impedimetric humidity sensors

Int J Biol Macromol. 2022 Jan 1:194:377-383. doi: 10.1016/j.ijbiomac.2021.11.079. Epub 2021 Nov 18.

Abstract

Nanocomposites of chitosan and cerium oxide‑cadmium oxide (CeO2-CdO) nanopowder were developed to fabricate impedimetric humidity sensors. The low temperature-stirring was used to synthesize CeO2-CdO nanopowder. Average particle size of synthesized nanopowder was 100 ± 20 nm. Various composition of chitosan-CeO2-CdO nanocomposites were developed using echo-friendly (mechanical mixing) technique. Pellets of 13.0 mm diameter and 1.0 ± 0.1 mm thickness were prepared using hydraulic press under the pressure of 375 MPa. Silver paste was used to deposit the electrodes; the length of each electrode was 12.0 mm and the gap between two electrodes was 2.0 ± 0.5 mm. The mechanism of sensing is based on impedimetric change in response to humidity variation. Fabricated sensors showed high sensitivities ranging from -930.0 kΩ/%RH to -2091.1 kΩ/%RH. Response and recovery times are up to 1 s, while the humidity sensing range is 5 to 95%RH. The fabricated sensors are very attractive to use in several devices for environmental monitoring and biomedical applications.

Keywords: Biomedical devices; Capacitance; Frequency; Impedance; Mechanical mixing; Pressing.

MeSH terms

  • Cadmium Compounds / chemistry*
  • Cerium / chemistry*
  • Chemical Phenomena
  • Chemistry Techniques, Synthetic
  • Chitosan / chemistry*
  • Humidity*
  • Nanocomposites / chemistry*
  • Nanocomposites / ultrastructure
  • Oxides / chemistry*
  • Spectrum Analysis

Substances

  • Cadmium Compounds
  • Oxides
  • cadmium oxide
  • Cerium
  • ceric oxide
  • Chitosan