Fast synthesis of porous iron doped CeO2 with oxygen vacancy for effective CO2 photoreduction

Abstract

The activity of photocatalytic CO₂ conversion to carbon-containing products is determined by the adsorption and activation of CO₂ molecules on the surface of catalyst. Here, iron doped porous CeO₂ with oxygen vacancy (PFeCe) was prepared by one-step combustion method. The amount of CO₂ adsorbed via using the porous structure has been significantly increased in the case of a relatively small specific surface area and CO₂ molecules are more easily captured and undergo a reduction reaction with photoinduced carriers. In addition, oxygen vacancies are formed in the iron doped CeO₂ lattice as the active sites for CO₂ reduction, which can form strong interactions with CO₂ molecules, thereby effectively activating CO₂ molecules. The reduction products of CO₂ over PFeCe composite are CO and CH₄, which is approximately 9.0 and 7.7 folds than that of CeO₂. This work offers insights for the construction of efficient ceria-based photocatalysts to further achieve robust solar CO₂ conversion.

Keywords: CO(2) reduction; Ceria; Oxygen vacancy; Photocatalytic; Porous structure.