Carbon materials modified with pores and heteroatoms have been pursued as promising electrode for supercapacitors due to the synergic storage of electric double-layer capacitance (EDLC) and pseudocapacitance. A vital problem that the actual effect of pores and heteroatoms on energy storage varies with the carbon matrix used presents in numerous carbon electrodes, but is ignored greatly, which limits their sufficient utilization. Moreover, most of modified carbon electrodes still suffer from severe capacitance degeneration under high mass load caused by the blocked surface and inaccessible bulk phase. Here, we shape an interconnected hollow carbon sphere (HCS) as the matrix by regulating and selectively-etching low molecular weight component in the inhomogeneous precursors, accompanied with the decoration of rich oxygen groups (15.9at%) and micropores (centering at 0.6-1.4 nm). Finite-element calculation and energy storage kinetics reveal the modified HCS electrode exposes accessible dual active surface with highly-matched electrons and ions for pores and oxygen groups to improve both EDLC and pseudocapacitance. Under a commercial-level load of 11.2 mg cm-2, the HCS exhibits a high specific capacitance of 288.3 F g-1 at 0.5 A g-1, performing a retention of 91.8% relative to 314 F g-1 under 2.8 mg cm-2 load, applicable for solar charging station to efficiently drive portable electronics.
Keywords: Carbon spheres; Hollow structure; Pores and heteroatoms; Renewable energy; Supercapacitors.
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