Membrane separation is able to efficiently remove pathogens like bacteria and viruses from water based on size exclusion. However, absolute and fast removal of pathogens requires highly permeable but selective membranes. Herein, we report the preparation of such advanced membranes using carbon nanotubes (CNTs) as one-dimensional building blocks. We first disperse CNTs with the help of an amphiphilic block copolymer, poly(2-dimethylaminoethyl methacrylate)-block-polystyrene (PDMAEMA-b-PS, abbreviated as BCP). The PS blocks adsorb on the surface of CNTs via the π-π interaction, while the PDMAEMA blocks are solvated, thus forming homogeneous and stable CNT dispersions. We then spray the CNT dispersions on porous substrates, producing composite membranes with assembled CNT layers as the selective layers. We demonstrate that the optimized membrane shows 100% rejection to phage viruses and bacteria (Escherichia coli) while giving a water permeance up to ∼3300 L m-2 h-1 bar-1. The performance of the resultant BCP/CNT membrane outperforms that of state-of-the-art membranes and commercial membranes. The BCP/CNT membrane can be used for multiple runs and regenerated by water rinsing. Membrane modules assembled from large-area membrane sheets sustain the capability of absolute and fast removal of viruses and bacteria.
Keywords: bacterium; block copolymer; carbon nanotube; spray coating; virus.