Preparation of sludge-based materials and their environmentally friendly applications in wastewater treatment by heterogeneous oxidation technology

Abstract

The sludge resource utilization and the high value-added development are environmentally friendly means for sludge treatment. With its rich organic substances and metals content, sludge can replace activated carbon and become a widely used carbon-based material, such as sludge-based activated carbon (SBAC). Meanwhile, as a heterogeneous catalyst, sludge-based catalyst (SBC) can solve the requirements of traditional Fenton catalysts for pH, metal ion leaching, and catalyst recycling. In this paper, combining the properties of SBAC/SBCs, the characteristics of the three methods of activation, support, and hydrothermal preparation of SBAC/SBCs are reviewed. In general, it is necessary to select an appropriate preparation method based on pollutants and environmental treatment goals. Furthermore, compared with other catalysts, SBC heterogeneous oxidation has obvious advantages in refractory organic pollutants. And the reaction mechanism usually involves SO₄·^-, ·OH, O₂·^-, and ¹O₂ processes. Finally, some possible directions for future research involving environmentally friendly SBAC/SBCs are proposed.

Keywords: Environmentally friendly; Heterogeneous oxidation; Refractory organics; Sludge-based activated carbon; Sludge-based catalysts; Synergistic catalysis.