Evaluation of photodegradation performance by paper microzones

Abstract

Currently, the performance evaluation of catalysts usually requires expensive instruments. Hence, it is imperative to develop an alternative, green and sustainable method to investigate the photocatalytic reaction processes. Herein, the variation of degradation performance of different wastewaters with different dosage of P25 TiO₂ was evaluated to verify the reliability of the paper microzones method (PMZs). The optimum P25 TiO₂ dosage of 1 g/L for the degradation of methylene blue (MB) (UV light for 6 mins) and 0.5 g/L for the degradation of fuchsin basic (FB) (UV light for 5 mins) was obtained by the PMZs method. For the photocatalytic degradation of trivalent iron ion complexed salicylic acid (Fe(III)-SA) solution, the R² values of 0.904 and 0.801 were obtained for the photocatalytic reaction kinetics by PMZs and spectrophotometry, respectively, which again indicated the high reliability of PMZs. The accuracy of the results obtained by PMZs method relative to the spectrophotometric method ranged from 68.80% to 87.54% when degrading MB, FB, mixture of MB and FB, and Fe(III)-SA by P25 TiO₂. Therefore, the PMZs method is all in line with the requirements of low-carbon environmental protection and green chemistry, and has broad application prospects in the future.

Keywords: P25 TiO(2); Paper microzones; Photocatalytic performance; Rapid test; Salicylic acid complexed Fe.