Adsorption isotherms and kinetics for the removal of algal organic matter by granular activated carbon

Abstract

Seasonal algal blooms in surface water release a significant amount of algal organic matter (AOM), which alters the composition of dissolved organic matter (DOM). AOM affects the drinking water treatment processes and finished water quality. In this study, the relative removal efficiency of AOM and humic acid by granular activated carbon (GAC) adsorption was determined. Batch experiments were conducted to evaluate the adsorption capacity of GAC, which varied from 4.235-31.45 mg/g for AOM originated from different algae. Freundlich isotherm models fitted the adsorption equilibrium data, and the adsorption kinetics data were fitted well using a pseudo-second order kinetic model. The calculated thermodynamics parameters (∆G⁰, ∆H⁰ and ∆S⁰) indicated that GAC adsorption for DOM removal was endothermic and spontaneous in nature.

Keywords: Adsorption isotherm; Algal organic matter; Granular activated carbon; Humic acid; Kinetics of adsorption.