Curly fish scales-like Ni2.5Mo6S6.7 electrodeposited on PEDOT-rGO with uneven surface as ultrafast response electrode for electrocatalytic glucose, nitrite and hydrogen peroxide

Abstract

The difficulty to achieve rapid detection is the limitation of many enzyme-free sensors today. Thus, designing tri-functionalsensors with ultra-fast and efficientdeterminationis a challenging taskin biological science. Herein, curly fish scales-like Ni_2.5Mo₆S_6.7 active materials was anchored on poly (3,4-ethylenedioxythiophene)-reduced graphene oxide (PEDOT-rGO) hybrid membranes with uneven surface (Ni_2.5Mo₆S_6.7/PEDOT-rGO) as a high-performance tri-functional catalyst for glucose, nitrite and hydrogen peroxide determination.The sensor constructed under optimal conditions exhibited ultrafast response performance towards glucose and nitrite within 2 s, and hydrogen peroxide within 1 s. Meanwhile, it provided the wide linear range with a low detection limit towards glucose (as low as 0.001 mM and up to 15.000 mM, and 0.33 μM), nitrite (as low as 0.001 mM and up to 10.000 mM, and 0.33 µM) and hydrogen peroxide (from 0.010 mM to 7.000 mM, and 0.79 μM), respectively. In addition, the sensor demonstrated satisfied selectivity, repeatability, reproducibility and stability. Furthermore, the sensor has potential application in real samples. This study may provide a new strategy for the construction of tri-functional electrode materials with the ultra-fast response.

Keywords: Glucose, nitrite and hydrogen-peroxide; Ni(2.5)Mo(6)S(6.7)/PEDOT-rGO; Real samples; Tri-functional; Ultra-fast response.