Passive sampling of chlorophenols in water and soils using diffusive gradients in thin films based on β-cyclodextrin polymers

Abstract

Chlorophenols (CPs) have been listed as priority control pollutants because of their high toxicity and wide range. An In-situ monitoring technique using diffusive gradients in thin films based on porous β-cyclodextrin polymers as binding materials (CDP-DGT), was established to monitor four typical CPs, namely, 4-Chlorophenol (4-CP), 2,4-Dichlorophenol (2,4-DCP), 2,4,5-Trichlorophenol (2,4,5-TCP), 2,4,6-Trichlorophenol (2,4,6-TCP) in water and soils. The performance of CDP-DGT are stable under the conditions of pH 3.5-9.3, ionic strength 0.001-0.500 mol L^-1 and dissolved organic matter concentration 0-20 mol L^-1. The adsorption capacities of CDP-DGT for 4-CP, 2,4-DCP, 2,4,5-TCP, 2,4,6-TCP were 57.80 μg cm^-2, 98.82 μg cm^-2, 95.69 μg cm^-2 and 98.91 μg cm^-2, respectively. The time-average weighted concentrations of four CPs determined by CDP-DGT at Sanjiangkou wharf (Yangtze river, China) were consistent with the results of grab sampling, indicating the feasibility of CDP-DGT application in actual water. In addition, the distribution of CPs in the red soil of Kunming and paddy soil of Yixing were also studied by CDP-DGT, and the desorption kinetics in the two soils were analyzed with the DIFS model. The higher the soil organic matter content is, the more CPs are distributed in the soil solid phase. CPs in both soils can be partially resupplied to soil solution from the soil solid phase and the higher the partition coefficient for labile CPs is, the stronger the supplement capacity is.

Keywords: Chlorophenols; Diffusive gradients in thin films; Passive sampling; β-Cyclodextrin polymers.