Carbon Nanotube Reinforced Poly(ε-caprolactone)/Epoxy Blends for Superior Mechanical and Self-Sensing Performance in Multiscale Glass Fiber Composites

Polymers (Basel). 2021 Sep 18;13(18):3159. doi: 10.3390/polym13183159.

Abstract

In this paper, a novel carbon nanotube (CNT) polycaprolactone (PCL), epoxy, and glass fiber (GF) composite is reported. Here, the nanoreinforced composites show a flexural strength increase of around 30%, whereas the interlaminar shear strength increases by 10-15% in comparison to unenhanced samples. This occurs because the addition of the CNTs induces a better PCL/epoxy/GF interaction. Furthermore, the nanoparticles also give novel functionalities to the multiscale composite, such as strain and damage monitoring. Here, the electrical response of the tensile- and compressive-subjected faces was simultaneously measured during flexural tests as well as the transverse conductivity in interlaminar tests, showing an exceptional capability for damage detection. Moreover, it was observed that the electrical sensitivity increases with PCL content due to a higher efficiency of the dispersion process that promotes the creation of a more uniform electrical network.

Keywords: carbon nanotubes; damage detection; interlaminar properties; multiscale composites; smart materials.