Adsorption of copper (II) and cadmium (II) ions by in situ doped nano-calcium carbonate high-intensity chitin hydrogels

Abstract

Most natural polymers exhibit limited functional groups, which is not favourable for the adsorption of various ions and their utilisation. To overcome this drawback, a novel in-situ-doped nano-calcium carbonate (CaCO₃) chitin hydrogel was synthesised as an efficient adsorbent for Cu (II) and Cd (II) ions. Scanning electron microscopy and Brunauer-Emmett-Teller results revealed that the synthesised CaCO₃/chitin hydrogel exhibited loose macropores and mesopores. Subsequently, Fourier transform infrared, Raman, and X-ray diffraction characterisation characterisation proved that chitin was successfully doped with nano-CaCO₃. The mechanical properties of CaCO₃/chitin hydrogel were superior to those of the unmodified chitin hydrogel and could efficiently adsorb Cu (II) and Cd (II) ions in water. The effect of pH, initial concentration, adsorbent dosage, and temperature was assessed to determine the adsorption properties of the hydrogel. Under suitable experimental conditions, the maximum adsorption rate of the CaCO₃/chitin hydrogel was approximately 96%. The time-dependent adsorption kinetics followed a quasi-second order model, and the adsorption process followed the Langmuir model. The maximum adsorption capacities of Cu (II) and Cd (II) according to the Langmuir curve were 194.61 and 191.58 mg/g, respectively. Compared with the binary competitive system, the material exhibited a specific selectivity to the adsorption of Cu (II). X-ray photoelectron spectroscopy (XPS) revealed that nitrogen and oxygen atoms were involved in chelation with the metal ions. The successful compounding of calcium carbonate nanoparticles provided more active adsorption sites for the gel. The novel material exhibited excellent adsorption effects on Cu (II) and Cd (II) ions when applied to a water sample. Thus, the novel material exhibits excellent potential for application. The Cu (II) and Cd (II)ion removal efficiencies after five successive adsorption cycles were higher than 90%, which indicated that the composite material exhibited excellent stability and reproducibility.

Keywords: Adsorption; Chitin hydrogel; Cu (II) and Cd (II); Nano-calcium carbonate.