Recent progress of silver-containing photocatalysts for water disinfection under visible light irradiation: A review

Abstract

Photocatalysis has emerged as an environmentally friendly approach for microbial disinfection. The development of visible-light-driven (VLD) photocatalysts for water pollution remediation is imperative, considering that visible light constitutes a substantial fraction of the solar spectrum. The modification of photocatalysts by Ag/AgX (X = Cl, Br, I) deposition can be used to improve photocatalytic efficiencies. This is achieved by preventing photogenerated electron-hole pairs recombination through electron trapping mechanisms. With the introduction of silver NPs, visible light absorption can also be increased through its SPR enhancement. Silver also possesses excellent antimicrobial properties. Consequently, a novel class of Ag/AgX-containing hybrid materials has recently emerged as a promising candidate for water disinfection. This review summarizes the latest advances in the synthesis of Ag/AgX-containing photocatalysts using various synthetic methods. The microbial disinfection efficiencies of the as-prepared materials, the main reactive oxygen species and disinfection mechanisms are also reviewed in detail. Finally, some areas that need to be improved are discussed along with new insights as perspectives for future developments in this field.

Keywords: Ag/AgX-containing photocatalyst; Disinfection; Visible light; Water treatment.