Porphyrins and Polyoxometalate Scaffolds

Chemistry. 2021 Nov 22;27(65):16071-16081. doi: 10.1002/chem.202102277. Epub 2021 Oct 8.

Abstract

Polyoxometalates (POMs) can act as unique reservoirs for multiple electron transfers. As POMs display only weak absorption in the visible spectrum, they can be associated with chromophores such as porphyrins and porphyrin antennae. In this Minireview, the research dedicated to the combination of porphyrins and polyoxometalates is put in context and the state of the art identifying the challenges addressed in the optimization of hybrid materials for applications is detailed.

Keywords: Electrochemistry; Photochemistry; Polyoxometalates; Porphyrins; Self-Organization.

Publication types

  • Review

MeSH terms

  • Electron Transport
  • Porphyrins*
  • Tungsten Compounds*

Substances

  • Porphyrins
  • Tungsten Compounds
  • polyoxometalate I