Electrically Tuneable Optical Diffraction Gratings Based on a Polymer Scaffold Filled with a Nematic Liquid Crystal

Polymers (Basel). 2021 Jul 13;13(14):2292. doi: 10.3390/polym13142292.

Abstract

We present an experimental and theoretical investigation of the optical diffractive properties of electrically tuneable optical transmission gratings assembled as stacks of periodic slices from a conventional nematic liquid crystal (E7) and a standard photoresist polymer (SU-8). The external electric field causes a twist-type reorientation of the LC molecules toward a perpendicular direction with respect to initial orientation. The associated field-induced modification of the director field is determined numerically and analytically by minimization of the Landau-de Gennes free energy. The optical diffraction properties of the associated periodically modulated structure are calculated numerically on the basis of rigorous coupled-wave analysis (RCWA). A comparison of experimental and theoretical results suggests that polymer slices provoke planar surface anchoring of the LC molecules with the inhomogeneous surface anchoring energy varying in the range 5-20 μJ/m2. The investigated structures provide a versatile approach to fabricating LC-polymer-based electrically tuneable diffractive optical elements (DOEs).

Keywords: diffractive optical elements; laser-based micro structuring; nematic liquid crystals; photoresist polymeric materials.