Biosorbents from Plant Fibers of Hemp and Flax for Metal Removal: Comparison of Their Biosorption Properties

Molecules. 2021 Jul 10;26(14):4199. doi: 10.3390/molecules26144199.

Abstract

Lignocellulosic fibers extracted from plants are considered an interesting raw material for environmentally friendly products with multiple applications. This work investigated the feasibility of using hemp- and flax-based materials in the form of felts as biosorbents for the removal of metals present in aqueous solutions. Biosorption of Al, Cd, Co, Cu, Mn, Ni and Zn from a single solution by the two lignocellulosic-based felts was examined using a batch mode. The parameters studied were initial metal concentration, adsorbent dosage, contact time, and pH. In controlled conditions, the results showed that: (i) the flax-based felt had higher biosorption capacities with respect to the metals studied than the hemp-based felt; (ii) the highest removal efficiency was always obtained for Cu ions, and the following order of Cu > Cd > Zn > Ni > Co > Al > Mn was found for both examined biosorbents; (iii) the process was rapid and 10 min were sufficient to attain the equilibrium; (iv) the efficiency improved with the increase of the adsorbent dosage; and (v) the biosorption capacities were independent of pH between 4 and 6. Based on the obtained results, it can be considered that plant-based felts are new, efficient materials for metal removal.

Keywords: biosorption; felt; flax; hemp; lignocellulosic fiber; metals.

MeSH terms

  • Adsorption
  • Cannabis / chemistry*
  • Flax / chemistry*
  • Lignin / chemistry
  • Metals, Heavy / analysis*
  • Metals, Heavy / isolation & purification*
  • Metals, Heavy / metabolism
  • Water Pollutants, Chemical / analysis*
  • Water Pollutants, Chemical / isolation & purification*
  • Water Pollutants, Chemical / metabolism
  • Water Purification / methods*

Substances

  • Metals, Heavy
  • Water Pollutants, Chemical
  • lignocellulose
  • Lignin