Potentially toxic elements leachates from cigarette butts into different types of water: A threat for aquatic environments and ecosystems?

Abstract

Trillions of cigarette butts (CBs) are released into the environment and the leached potentially toxic elements (PTEs) from CBs may contaminate the environments. In this study, the leaching of PTEs including both heavy metals and metalloids (metal(loid)s) from CBs into deionized water (DW), tap water (TW), and seawater (SW) was checked during the different contact times (from 60 min to 60 days). According to the results, PTEs were leached from CBs into different water samples. However, there were no significant differences between leachates in DW and TW samples (p > 0.05). The results of the distribution coefficient indicated the high tendency of most PTEs to enter the liquid phase. The levels of leached PTEs into DW and TW exceeded the standards of surface freshwater to maintain aquatic life. Although the maximum level of leached metal(loid)s into DW, TW, and SW occurred at different times, for each type of water sample no significant differences were found among the levels of most PTEs at various contact times. Based on the results, the levels of leached metal(loid)s from CBs in seawater peak soon after being released into the water, while for the freshwater, they occur after some days. This phenomenon could possibly have short-term and long-term effects on marine and freshwater organisms, respectively. Due to the ability of the dissolved PTEs to integrate into the aquatic/terrestrial food web and threaten human health, some control measures regarding the disposal of CBs are necessary.

Keywords: Cigarette butts; Distribution coefficient; Ecological risk; Emission rates; Monte-Carlo simulation; The Persian Gulf.