Emergence of quenched disorder as a dominant control for complex phase diagram of rare-earth nickelates

Abstract

Competing interactions in complex materials tend to induce multiple quantum phases of comparable energetics close to the ground state stability. This requires novel strategies and tools to segregate such phases with desired control to manipulate the properties relevant for contemporary technologies. Here, we show 'quenched disorder (QD)' as a predominant control parameter to realize a broad range of the quantum phases of bulkRNiO₃(R= rare-earth ion) phase diagram in a La_xEu_1-xNiO₃compounds by systematic introduction of QD. Using static and terahertz dynamic transport studies on epitaxial thin films, we demonstrate various phases such as Fermi to non-Fermi liquid crossover, bad metallic behavior, quantum criticality, preservation of orbital and charge order symmetry and increased electronic inhomogeneity responsible for Maxwell-Wagner type of dielectric response, etc. The underlying mechanisms are unveiled by the anomalous responses of microscopic quantities such as scattering rate, plasma frequency, spectral weight, effective mass, and disorder. The results and methodology implemented here can be a generic pursuit of disorder based unified control to extract quantum phases submerged in competing energetics in all complex materials.

Keywords: Fermi liquid; bad metallicity; metal–insulator transition; phase-diagram; quantum criticality; quenched disorder; rare earth nickelates.