Co-microwave pyrolysis of electroplating sludge and municipal sewage sludge to synergistically improve the immobilization of high-concentration heavy metals and an analysis of the mechanism

Abstract

To improve the harmless treatment of high-concentration heavy metals (HMs) in electroplating sludge (ES), this study tried to combine the microwave pyrolysis technology and the addition of municipal sewage sludge (MS) to synergistically improve the immobilization of high-concentration HMs in ES. The results showed that the immobilization rate of HMs was less than 75% in ES pyrolysis biochar. Notably, the immobilization rate of HMs up to 98.00% in co-pyrolysis biochar. Finally, it was found by various characterizations that the organic carbon and inorganic minerals in MS played an important role in the immobilization of HMs through physical and chemical effects. HMs reacted with inorganic minerals to form HMs crystalline minerals (e.g., CuCl, Cu₂NiSnS₄, and NiSi₂, ZnS) to realize the immobilization of HMs. The addition of organic carbon was conducive to the formation of biochar with higher carbon crystallinity (I_D/I_G = 0.96) and larger specific surface area (52.50 m² g^-1), thereby enhancing the physical adsorption to HMs. Meanwhile, the complexation reaction between HMs and functional groups such as -OH, Si-O-Si could also further improve the immobilization of HMs. Therefore, this study provided a technical and theoretical basis for the harmless disposal of waste containing multiple HMs with high-concentrations.

Keywords: Co-microwave pyrolysis; Electroplating sludge; High-concentration heavy metals; Immobilization.