Synthesis of the cathode and anode materials from discarded surgical masks for high-performance asymmetric supercapacitors

Abstract

Advanced carbon-based electrode materials derived from wastes are essential to high-performance supercapacitors due to their abundance and sustainability. In this work, we fabricate novel cathodes and anodes based on discarded surgicalmask-derived carbon (DSM-C). Discarded surgicalmasks are good candidates for carbon-based electrode materials due to their unique fibrous structure and simple composition compared to conventional biomass sources. Benefiting from the excellent electrical conductivity of DSM-C and abundant redox reactions from nickel oxide (NiO), the electrochemical performances of NiO/DSM-C composites have been greatly improved. Specifically, the DSM-C and NiO/DSM-C electrodes show high specific capacitances of 240 F g^-1 and 496 F g^-1 at 1 A g^-1 respectively, and excellent rate capability. Moreover,asymmetric supercapacitors (ASCs) are assembled using DSM-C and NiO/DSM-C as anodes and cathodes, respectively. They deliver a high energy density of 57 Wh kg^-1 at a power density of 702 W kg^-1, accompanied by superior cycling stability (98.5% capacitance retention after 10,000 cycles). This work shows prospective applications of DSM-C as an electrode material for energy storage systems.

Keywords: Asymmetric supercapacitors; Discarded surgicalmasks; NiO.