Ternary Zn1-xNixSe nanostructures as efficient photocatalysts for detoxification of hazardous Congo red, methyl orange, and chrome yellow dyes in wastewater sources

Abstract

Water contamination by hazardous organic pollutants poses an extreme threat to the environment and globally endangers aquatic life and human health. Hence, the removal of toxic organic effluents from water sources is necessary to ensure a healthy green environment. To this end, a new class of emerging, visible-light-driven Zn- and Ni-based ternary metal-selenide (Zn_1-xNi_xSe) nanophotocatalysts, with tunable nanostructures via regulation of the stoichiometric ratios of Zn and Ni, were synthesized for efficient water purification by a facile one-pot hydrothermal process. These catalysts exhibit outstanding porous properties, with large surface areas and average particle sizes of around 80 ± 10 nm. The as-prepared ternary Zn_1-xNi_xSe catalysts enable improved optical properties, intrinsic conductivity, bandgap reductions, and large numbers of active sites compared with pristine materials, thereby exhibiting outstanding degradation properties against various dye molecules, including Congo red, methyl orange, and chrome-IV upon visible light irradiation. The improved photodegradation capabilities of the Zn_1-xNi_xSe catalysts may be attributed to the synergistic combinations of Zn and Ni selenides, which in turn minimize the recombination rates of the photogenerated carriers compared to their individual constituents. These findings clearly demonstrate that the proposed ternary Zn_1-xNi_xSe catalysts could be potentially used to remove toxic organic contaminants from industrial wastewater.

Keywords: Nanoporous; Organic dye molecules; Photodegradation; Wastewater treatment; Zinc-nickel selenide.