With the development of sensing technologies and machine learning, techniques that can identify emotions and inner states of a human through physiological signals, known as electroencephalography (EEG), have been actively developed and applied to various domains, such as automobiles, robotics, healthcare, and customer-support services. Thus, the demand for acquiring and analyzing EEG signals in real-time is increasing. In this paper, we aimed to acquire a new EEG dataset based on the discrete emotion theory, termed as WeDea (Wireless-based eeg Data for emotion analysis), and propose a new combination for WeDea analysis. For the collected WeDea dataset, we used video clips as emotional stimulants that were selected by 15 volunteers. Consequently, WeDea is a multi-way dataset measured while 30 subjects are watching the selected 79 video clips under five different emotional states using a convenient portable headset device. Furthermore, we designed a framework for recognizing human emotional state using this new database. The practical results for different types of emotions have proven that WeDea is a promising resource for emotion analysis and can be applied to the field of neuroscience.