A novel cluster fusion method is proposed, based on which chaos synchronization in asymmetric coupling semiconductor lasers (ACSLs) networks is systematically demonstrated. Take the cluster fusion of a mutually-coupled network composed of 7 semiconductor lasers (SLs) for instance, the characteristics of chaos synchronization as well as the influences of coupling strength, bias current, and mismatches of intrinsic parameters and injection strength on the quality of chaos synchronization in hybrid clusters composed of ACSLs are thoroughly investigated. The results show that by using cluster fusion, the ACSLs which originally belong to different clusters can form three types of new hybrid clusters, namely, trivial-hybrid cluster, trivial-nontrivial-hybrid cluster, and nontrivial-hybrid cluster. Compared with the low-correlation inter-cluster ACSLs of original SLs network, high-quality chaos synchronization is achieved in three types of newly generated hybrid clusters over a wide parameter range. Moreover, the cluster fusion and synchronization of side-SLs clusters of star-type SLs networks are also verified, which indicate the universality of the proposed method. This work provides a new way to realize the chaos synchronization among ACSLs of different clusters.