Environmental implications of one-century COPRs evolution in a single industrial site: From leaching impact to sustainable remediation of CrVI polluted groundwater

Abstract

The Stoppani factory manufactured chromium for more than one century, dumping millions of tons of Chromite Ore Processing Residues (COPRs) over decades. The massive presence of COPRs resulted in an intense Cr^VI leaching and consequent contamination of percolating groundwater. The site offers a unique opportunity to follow COPRs evolution from the primary roasting process to the aged Cr-bearing mineral phases. Herein, new insights on COPRs mineralogy evolution and their role in Cr^VI release are provided by a dry sample preparation protocol, coupled with in-depth multi-technique characterization. Besides typical COPRs mineral assemblages, highly soluble Na₂CrO₄ and the first evidence of crocoite (PbCrO₄) in a COPR contaminated site are revealed. Selective extraction experiments confirmed a strong reactivity for Cr-bearing minerals as confirmed by concentrations as high as 375 mg L^-1 of leached Cr^VI. The mineralogical approach was combined with a nanotechnological solution for Cr^VI wastewater remediation. The application of naked colloidal maghemite (γ-Fe₂O₃) nanoparticles (SAMNs) on the complex industrial wastewater, led to > 90% Cr^VI removal, either under acidic or in-situ conditions. The present case study of a highly polluted site, ranging from mineral characterization to wastewater remediation, highlights the use of multidisciplinary approaches to cope with complex environmental issues.

Keywords: Chromite ore processing residues; Chromium; Crocoite; Iron oxide nanoparticles; Mineralogy.